It might be a noob question and we're all 'noobs' at one point.
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I don't know that much of computers, but yes, game should work fine (even all maxed out).
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However, you should turn all the eye-candy things off from you're Vista. It slows down everything when you play games.
I won't use Vista with games anymore since it eats lots of resources and sucks with games in my opinion. I prefer XP more!
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But yes, game should work as I said before.
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If I'm wrong just correct me.